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filingDate 2019-04-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-05-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2021-05-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-110102335-B
titleOfInvention SBA-16-based CO selective methanation nickel-based catalyst and preparation method thereof
abstract The invention discloses a CO selective methanation nickel-based catalyst based on SBA-16 and a preparation method thereof. The catalyst comprises Ni as an active component and Ti-doped Ti-SBA-16 as a carrier. The method comprises the steps of taking isopropyl titanate dissolved in an organic solvent as a titanium source, fully adsorbing the isopropyl titanate on the surface of a mesoporous molecular sieve SBA-16, preparing a Ti-doped mesoporous molecular sieve Ti-SBA-16 by a hydrolysis method, and finally loading an active component Ni on a Ti-SBA-16 carrier by an impregnation method to prepare the Ni/Ti-SBA-16 catalyst. The catalyst provided by the invention has uniform Ti distribution and high Ni dispersibility and stability, can reduce the content of 1vol% of CO in the hydrogen-rich reformed gas to below 10ppm at a lower temperature (170-210 ℃), has selectivity higher than 50%, and can be applied to the purification treatment of the hydrogen-rich fuel gas of the proton exchange membrane fuel cell.
priorityDate 2019-04-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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