http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-110003251-B

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filingDate 2019-04-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-08-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2021-08-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-110003251-B
titleOfInvention Preparation and application of dual-fluorescence response europium-based molecular crystalline material
abstract The preparation and application of the dual-fluorescence response europium-based molecular crystalline material are as follows: { [ Eu (BCPT) (HCOO)] . H 2 O} n Wherein BCPT is 4,4' - (4 hydrogen-1, 2, 4-triazole-3, 5-) dibenzoate anion ligand, and HCOO is formate anion decomposed by N, N-dimethylformamide. The dual fluorescent response europium-based molecular crystalline material is crystalline in an orthorhombic system with a spatial group of Pnma, unit cell parameters a =6.68250(19) a, b =36.4612(9) a, c =13.0981(3) a, α =90 °, β =90 °, γ =90 °, V =3191.38(14) a 3 . The dual-fluorescence response europium-based molecular crystalline material has better stability, acid resistance and alkali resistance to organic solvents and boiling water, has simple preparation process and mild reaction conditions, and is easy for mass preparation. The material of the invention simultaneously shows excellent selective fluorescence recognition effect on acetylacetone and phosphate radical, can be simultaneously used for recognizing acetylacetone pollutants in liquid phase and phosphate radical ion pollutants in water environment, and has the characteristics of good specificity, high selectivity and the like.
priorityDate 2019-04-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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Total number of triples: 32.