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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G63-08
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G63-87
filingDate 2018-12-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_3e1c2e39a434641cb10b3ba1e2d40316
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publicationDate 2019-06-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-109851765-A
titleOfInvention A kind of organic concerted catalysis lactone ring opening polymerization without metal catalyst system
abstract The invention discloses a kind of organic concerted catalysis lactone ring opening polymerizations without metal catalyst system, which belongs to high molecular synthetic material field, the controllable active ring-opening polymerisation applied to efficient catalyzing lactone.Preparation method of the present invention is under inert gas protection, using lactone as monomer, in organic solvent, by alkene outside N- heterocycle and thiocarbamide concerted catalysis or by alkene outside N- heterocycle and urea concerted catalysis, and to cause lactone by alcohols and carry out ring-opening polymerization.In organic solvent, without metal residual in obtained aliphatic hydrocarbon polyester polymer, reaction condition is mild, rapid reaction, and polymerization process is simple to operation for this synthetic methodï¼›High conversion can be obtained, and the polyester material of narrow molecular weight distribution can be obtained under the action of few catalytic amount.
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priorityDate 2018-12-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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