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filingDate 2017-09-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2022-04-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2022-04-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-109789344-B
titleOfInvention Functionalized Polyolefin Capillaries for Open Tube Ion Chromatography
abstract Open-tube capillary columns for liquid and ion chromatography based on ion-impermeable polyolefin capillaries having pores with sulfonate- or amine-functionalized inner surfaces. The capillary column can include a coating of ion exchange nanoparticles electrostatically bound to the functionalized inner surface. Capillary columns can be produced by exposing the inner surface to a sulfonating reagent comprising chlorosulfonic acid ( ClSO3H ), preferably 85 to 95 wt% chlorosulfonic acid, at a process temperature of 20 to 25°C. The inner surface can then be exposed to an asymmetric diamine to form a sulfonic acid-based intermediate bond with the diamine, ie, a sulfonamide-linked amine-functionalized inner surface. The coating is then formed by exposing the inner surface to an aqueous suspension of ion-exchange nanoparticles to electrostatically bind the ion-exchange nanoparticles to the functionalized inner surface.
priorityDate 2016-09-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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