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filingDate 2019-02-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-04-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2021-04-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-109651450-B
titleOfInvention Fine-control polyacid Schiff base covalent composite material and preparation method and application thereof
abstract The invention discloses a finely-regulated polyacid Schiff base covalent composite material, and a preparation method and application thereof, wherein the composite material is synthesized by taking heteropolyacid [ IMO6] and Mn-Salen as precursors in a water-methanol mixed solvent in the presence of L-leucine. The invention solves the problems that the POM-Mn2salen system has a single structure and is difficult to regulate and control, and provides a new model for polyacid compound type supramolecular materials. The reaction condition of the invention is mild, and only water-alcohol mixed solvent is used; the reactants are modified to provide a good theoretical model for the development of the structure of the composite magnet material.
priorityDate 2019-02-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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