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filingDate 2018-11-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2019-03-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-109535473-A
titleOfInvention A kind of low water absorption crosslinked polyimide aeroge preparation method
abstract A kind of low water absorption crosslinked polyimide aeroge preparation method, it is related to a kind of aeroge preparation method, this method prepares polyamic acid solution first, aromatic dianhydride, aromatic diamine are gradually dissolved in intensive polar solvent according to molar ratio for 1.00 ~ 1.50:1, it is reacted at room temperature 5-8 hours in nitrogen atmosphere, obtains polyamic acid solution;Secondly the polyimides wet gel of preparation crosslinking, adamantane crosslinker is added into polyamic acid solution, the polyimides wet gel being crosslinked;The methods of third step, polyimides wet gel are dried, and normal pressure spontaneously dries and heat de-airing is dry drying can prepare low water absorption crosslinked polyimide aeroge;Products obtained therefrom water absorption rate low (1% ~ 20%), dielectric constant low (2.8 ~ 2.4), thermal stability are good (450 DEG C of thermal decomposition or more).The aeroge of low water absorption can be used for the field more demanding to steam such as aviation, ship, electronic equipment, have broad application prospects.
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