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filingDate 2018-10-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_7e91a73527dbdc5f0d189adb1264b91e
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publicationDate 2019-03-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-109535392-A
titleOfInvention A kind of fluorine-containing conjugated polyene alkine compounds and preparation method thereof
abstract The invention belongs to the technical field of high molecular material, a kind of fluorine-containing conjugated polyene alkine compounds and preparation method thereof are disclosed.The method: in protective atmosphere, binary alkynyl compounds and perfluoroalkyl iodide hydrocarbon compound are subjected to polymerization reaction in organic solvent, subsequent processing obtains fluorine-containing conjugated polyene alkine compounds;The binary alkynyl compounds: CH ≡ C-R 1 -C≡CH(Ⅱ);The perfluoroalkyl iodide hydrocarbon compound I-R 2 (Ⅲ);The structure of the fluorine-containing conjugated polyene alkine compounds is formula I, in formula (I)~(III), x, y, and the integer that z is 2~200, R 1 , R 2 For identical or different organic group.Method polymerizing condition of the invention is mild, simple process, and polymerization efficiency is high, and the yield of product is high, and molecular weight is high.Fluorine-containing conjugated polyene alkine compounds prepared by the present invention have preferable thermal stability and hydrophobic performance, have a good application prospect.
priorityDate 2018-10-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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