http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-109482229-B

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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J29-89
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D333-76
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J35-1061
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J37-0018
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D333-76
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J37-00
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J35-10
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J29-89
filingDate 2018-09-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-09-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2021-09-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-109482229-B
titleOfInvention Hierarchical pore titanium silicalite molecular sieve catalyst with oxidative desulfurization effect and preparation method and application thereof
abstract The invention belongs to the technical field of molecular sieves and preparation thereof, and discloses a hierarchical pore titanium silicalite molecular sieve catalyst with oxidative desulfurization, and a preparation method and application thereof. The preparation method comprises the following steps: mixing tetrapropylammonium hydroxide and deionized water, then dropwise adding ethyl silicate and butyl titanate, and stirring; transferring the mixture into a stainless steel autoclave, and statically drying in a drying oven at 180 ℃; centrifugally separating, washing, and drying in an oven at 80 ℃ overnight to obtain the molecular sieve; mixing a molecular sieve, sodium hydroxide, water and aspartic acid, stirring at room temperature, centrifugally filtering, drying filter residues in an oven at 80 ℃ for 10 hours, taking out the filter residues, heating the filter residues to 550 ℃ from room temperature at the speed of 2 ℃/min, and calcining the filter residues for 6 hours to obtain the catalyst. The conversion rate of the Si/Ti-20 molecular sieve catalyst for removing sulfide can reach 43% after 4h, and the reaction is a first-order kinetic reaction according to the kinetic simulation.
priorityDate 2018-09-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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