http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-109482229-B
Outgoing Links
Predicate | Object |
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classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J29-89 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D333-76 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J35-1061 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J37-0018 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D333-76 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J37-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J35-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J29-89 |
filingDate | 2018-09-30-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2021-09-07-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2021-09-07-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-109482229-B |
titleOfInvention | Hierarchical pore titanium silicalite molecular sieve catalyst with oxidative desulfurization effect and preparation method and application thereof |
abstract | The invention belongs to the technical field of molecular sieves and preparation thereof, and discloses a hierarchical pore titanium silicalite molecular sieve catalyst with oxidative desulfurization, and a preparation method and application thereof. The preparation method comprises the following steps: mixing tetrapropylammonium hydroxide and deionized water, then dropwise adding ethyl silicate and butyl titanate, and stirring; transferring the mixture into a stainless steel autoclave, and statically drying in a drying oven at 180 ℃; centrifugally separating, washing, and drying in an oven at 80 ℃ overnight to obtain the molecular sieve; mixing a molecular sieve, sodium hydroxide, water and aspartic acid, stirring at room temperature, centrifugally filtering, drying filter residues in an oven at 80 ℃ for 10 hours, taking out the filter residues, heating the filter residues to 550 ℃ from room temperature at the speed of 2 ℃/min, and calcining the filter residues for 6 hours to obtain the catalyst. The conversion rate of the Si/Ti-20 molecular sieve catalyst for removing sulfide can reach 43% after 4h, and the reaction is a first-order kinetic reaction according to the kinetic simulation. |
priorityDate | 2018-09-30-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 40.