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filingDate 2018-10-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2019-03-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-109449009-A
titleOfInvention One-dimensional manganese dioxide nanotube @ZIF-67 core-shell heterostructure composite material and preparation method and application thereof
abstract The invention discloses a one-dimensional manganese dioxide nanotube @ZIF‐67 core-shell heterostructure composite material and a preparation method and application thereof, the preparation method comprises the following steps: 1) dispersing a monomer MnO 2 nanotube and a cobalt source in an organic solvent Forming a mixed solution A; 2) dispersing 2-methylimidazole and a surfactant in an organic solvent to form a mixed solution B; 3) mixing the mixed solution A and the mixed solution B, and then performing a contact reaction, followed by post-treatment to obtain One-dimensional MnO 2 nanotube @ZIF‐67 core-shell heterostructure composite. The one-dimensional manganese dioxide nanotube @ZIF-67 core-shell heterostructure composite material has excellent electrochemical performance and can be applied to the supercapacitor electrode material, and the preparation method has the advantages of simple operation, low cost and mild condition. , green and other advantages.
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