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filingDate 2018-09-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2020-10-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2020-10-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-109265656-B
titleOfInvention Conjugated polymers substituted by dialkyl sulfide chains and their preparation and application
abstract The present invention relates to a conjugated polymer substituted by a dialkyl sulfide chain as shown in formula I: Wherein: R 1 is a C 8 -C 12 straight-chain alkyl group, a C 8 -C 12 branched-chain alkyl group or a C 8 -C 12 alkylthio group; R 2 is a hydrogen atom, a chlorine atom or a fluorine atom; and R 3 is a C 8 -C 12 straight chain alkyl group or C 8 -C 12 branched chain alkyl group; n represents the number of repeating units of the polymer, which is any natural number between 4-400. The present invention also provides an active layer of a polymer solar cell, comprising the above-mentioned bisalkylsulfide chain-substituted conjugated polymer donor shown in formula I and a non-fullerene n-type fused-ring acceptor molecule. The conjugated polymer of the present invention, as a polymer donor, exhibits excellent photovoltaic performance and good device stability when applied to organic solar cells. When the cell area is 0.04 cm 2 , the power conversion efficiency (PCE) reaches 13.10%, especially, when the device area is 1 cm 2 , it still reaches 10.21% power conversion efficiency.
priorityDate 2018-09-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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Total number of triples: 43.