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filingDate 2018-08-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2019-01-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-109261212-A
titleOfInvention Multi-oxygen cluster-double metal hydroxide composite, preparation thereof and method for heterogeneously catalyzing degradation of chemical warfare agent analog
abstract The invention relates to a polyoxonium-bimetallic hydroxide composite, a preparation thereof and a method for heterogeneously catalyzing degradation of a chemical warfare agent analog, and belongs to the field of catalytic chemistry. The composite consists of a layered magnesium aluminum double hydroxide, an interlayer polyoxonium anion, and an interlayer water molecule. The composite is dispersed in an aqueous solution of a polyoxane cluster by adding MgAl-LDH-NO 3 , and then added to the reaction vessel, sealed, and then reacted at 80 to 120 ° C for 1 to 3 days, and cooled to 20 to 30 ° C. Filtered and obtained after washing. When the composite is used for heterogeneously catalyzed degradation of chemical warfare agent analogs, CEES is highly selectively converted to a less toxic sulfoxide product, and the conversion rate is higher, reaching 95% or more; DECP is in the absence of additives. Efficient conversion to non-toxic products under conditions; OSDEMP highly selective cleavage P-S bond, resulting in less toxic products; mild catalytic conditions.
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