| abstract |
The invention discloses one kind (-) -2- (4 '-pyridyl group) -4,5- firpene-pyridine chirality silver complex, the molecular formula of complex is [Ag (L) ClO 4 ] ∞ , the present invention is by chiral monodentate organic ligand L:[(- containing N) -2- (4 '-pyridyl group) -4,5- firpene-pyridine] and AgClO 4 Reaction, obtained (-) -2- (4 '-pyridyl group) -4,5- firpene-pyridine chirality silver complex preparation method, simple process, normal temperature and pressure reaction, safety is good and at low cost, easy post-processing and yield is up to 86%；The complex, which not only has chiral optical activity also, has absorption ultraviolet light, generate the ability of VISIBLE LIGHT EMISSION, it is the bifunctional material simultaneously with chiral optical activity and light transfer capability, is expected to have wide commercial applications prospect in terms of circular polarised luminescence, fluoroimmunoassay, nonlinear optical material and light shifting molecular as advanced luminescent material. |