| abstract |
The invention discloses a kind of synthetic methods of aromatic amine compounds, it is characterized in that, carry out according to any one of following two method: method one: will have the alkyl-aromatic compounds of logical formula (I) mix with having the nitrogenous compound of logical formula (II), and reaction is obtained under the conditions of existing for the oxidant and organic solvent has the aromatic amine compounds for leading to formula (III)；Method two: will have the fragrant 01 derivatives of general formula (I ') mix with having the nitrogenous compound of logical formula (II), and the aromatic amine compounds that the logical formula (III) is made are reacted under the conditions of existing for the acid additive and organic solvent.The present invention is for the first time raw material using large alkyl-aromatic compounds or fragrant 01 derivatives, under the action of metal catalytic, reaction generates aromatic amine compounds, have high income, condition are simple, waste discharge amount is few, do not need metal to participate in compared with prior synthesizing method, many advantages, such as consersion unit is simple, easy to industrialized production, therefore, it is with a wide range of applications. |