http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-109053818-B

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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F110-02
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F15-045
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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F110-02
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F15-04
filingDate 2018-08-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-05-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2021-05-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-109053818-B
titleOfInvention Preparation of fluorinated nickel (II) complexes containing ortho-diphenylmethyl-substituted alpha-diimines for ethylene polymerization
abstract The invention belongs to the technical field of olefin polymerization, and discloses a novel fluorinated alpha-nickel diimine complex containing ortho-diphenylmethyl and a preparation method thereof, wherein the complex is applied to ethylene polymerization, introduces diphenylmethyl and F groups with large steric hindrance into the ortho-position of a phenyl group of a catalyst, changes the coordination environment (steric hindrance and electron density) of a metal center, and can effectively adjust catalytic activity, polymer molecular weight and a micro-branched structure under the activation of a cocatalyst MAO. The complex has high thermal stability when catalyzing ethylene polymerization, and polyethylene with high molecular weight and low branching degree is obtained.
priorityDate 2018-08-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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