http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-108947907-B
Outgoing Links
Predicate | Object |
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classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07B2200-13 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C09K2211-188 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D233-14 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/G01N21-643 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F1-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C09K11-06 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F1-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/G01N21-64 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C09K11-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D233-14 |
filingDate | 2018-08-14-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2021-06-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2021-06-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-108947907-B |
titleOfInvention | Azobenzene-linked cyclic N-heterocyclic carbene silver complex and preparation method and application thereof |
abstract | The invention discloses an azobenzene-linked N-heterocyclic carbene metal complex and a preparation method and application thereof. It is prepared through the reaction of o-nitrophenol with 1, 2-dibromoethane in organic solvent to obtain 2- (2 ' -bromoethoxy) nitrobenzene, and the reaction of the 2- (2 ' -bromoethoxy) nitrobenzene with 1-methylimidazole to obtain 1-methyl-3- [2- (2 ' -nitrophenoxy) ethyl]Imidazole bromide, which reacts with lead powder and triethylamine formate to obtain a product, and then the product is exchanged with hexafluorophosphate to obtain 2,2 ' -bis [2 ' ' - (E-N-methyl-N- N -methylimidazole) ethoxy)]An azobenzene hexafluorophosphate compound; then adding the bisimidazole hexafluorophosphate and a metal compound into a reaction vessel according to a certain proportion to react to obtain the N-heterocyclic carbene metal complex. The metal complex has the advantages of adjustable structure, simple preparation and obvious fluorescent photosensitive effect, can be used for manufacturing a fluorescent molecule recognition system, and is expected to be applied to the field of fluorescent chemistry. |
priorityDate | 2018-08-14-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 81.