http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-108947907-B

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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D233-14
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/G01N21-643
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http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C09K11-06
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F1-10
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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D233-14
filingDate 2018-08-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-06-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2021-06-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-108947907-B
titleOfInvention Azobenzene-linked cyclic N-heterocyclic carbene silver complex and preparation method and application thereof
abstract The invention discloses an azobenzene-linked N-heterocyclic carbene metal complex and a preparation method and application thereof. It is prepared through the reaction of o-nitrophenol with 1, 2-dibromoethane in organic solvent to obtain 2- (2 ' -bromoethoxy) nitrobenzene, and the reaction of the 2- (2 ' -bromoethoxy) nitrobenzene with 1-methylimidazole to obtain 1-methyl-3- [2- (2 ' -nitrophenoxy) ethyl]Imidazole bromide, which reacts with lead powder and triethylamine formate to obtain a product, and then the product is exchanged with hexafluorophosphate to obtain 2,2 ' -bis [2 ' ' - (E-N-methyl-N- N -methylimidazole) ethoxy)]An azobenzene hexafluorophosphate compound; then adding the bisimidazole hexafluorophosphate and a metal compound into a reaction vessel according to a certain proportion to react to obtain the N-heterocyclic carbene metal complex. The metal complex has the advantages of adjustable structure, simple preparation and obvious fluorescent photosensitive effect, can be used for manufacturing a fluorescent molecule recognition system, and is expected to be applied to the field of fluorescent chemistry.
priorityDate 2018-08-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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