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filingDate 2018-05-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-02-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2021-02-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-108620099-B
titleOfInvention Double-cavity magnetic Fe3O4@mSiO2@ BiOCl-Ag/AgBr composite material and preparation method thereof
abstract Double-cavity magnetic Fe 3 O 4 @mSiO 2 @ BiOCl-Ag/AgBr composite material with bell-shaped double-cavity structure comprising mSiO 2 @ BiOCl-Ag/AgBr mesoporous composite microsphere outer layer cavity and Fe 3 O 4 Magnetic hollow microsphereThe inner layer is a cavity. The invention also provides a preparation method of the composite material, which comprises the following steps: 1) stober process in Fe 3 O 4 Growing SiO on the surface of the microsphere 2 A layer; 2) synthesis of mSiO by CTAB micelle template method 2 a/CTAB composite layer; 3) etching the silicon dioxide intermediate layer; extracting CTAB; 4) performing surface amino functionalization on the mesoporous silicon dioxide layer through APTES; 5) obtaining double-cavity magnetic Fe through solvothermal reaction 3 O 4 @mSiO 2 @ BiOCl-Ag/AgBr composite material. The invention can realize effective treatment of the refractory organic pollutants by first enriching and then catalyzing and degrading.
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