http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-108569984-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_3966ddee295e08cc6fcce4695c77f91b |
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2601-16 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C249-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F5-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C251-18 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-0252 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F5-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C249-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C251-18 |
filingDate | 2018-05-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_5445f0c639aaffd675b5a7d36abd5899 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2e73b0e865907bab2e3de15e038de2b2 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4a81649fa8929685caf0e6b1a8218e3b http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_317f714f6f257a5040b8b2b097659f83 |
publicationDate | 2018-09-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-108569984-A |
titleOfInvention | A kind of unsymmetrical diimine monovalent magnesium compound and its preparation method and application in hydroboration reaction of alkylene oxide |
abstract | The invention discloses an unsymmetrical diimine monovalent magnesium compound, a preparation method thereof and an application in hydroboration reaction of alkylene oxide. For the first time, the present invention uses a monovalent magnesium compound to catalyze the reaction of alkylene oxide and pinacol borane to synthesize boric acid ester, which has high catalytic activity, simple structure and easy synthesis, and not only enriches the hydroboration reaction of alkylene oxide compound and borane The preparation of borate esters provides a new solution and expands the application of monovalent magnesium compounds. The monovalent magnesium compound of the present invention can catalyze the hydroboration reaction of alkylene oxide and borane with high activity. No matter it is aromatic alkylene oxide or fatty alkylene oxide, the amount of catalyst only needs 5% of the molar amount of the substrate, and the reaction options High property, mainly Martensitic addition products, can almost reach 100% conversion rate. The reaction selectivity is high, the reaction is simple and controllable, and it is highly in line with the concept of green chemistry. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-113398999-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-113058646-A |
priorityDate | 2018-05-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 29.