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filingDate 2018-04-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_a9bc19d392b919283c7a1d32e533e350
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publicationDate 2018-09-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-108558920-A
titleOfInvention 4 '-phenyl -2,2 ':The preparation method of 6 ', 2 ' '-terpyridyl nitric acid Gd coordination compound
abstract The invention discloses a kind of 4' phenyl 2,2 ':The preparation method of 6 ', 2 ' ' terpyridyl nitric acid Gd coordination compound.Weigh 4' phenyl 2,2 ':6 ', 2 ' ' terpyridyl is dissolved in obtained solution in dichloromethane, and solution is moved into reaction kettle;It weighs gadolinium nitrate hexahydrate and is dissolved in acetonitrile obtained gadolinium nitrate hexahydrate solution, gadolinium nitrate hexahydrate solution is added in reaction kettle, then reaction kettle is placed in electric drying oven with forced convection, isothermal reaction 48 hours at 80 DEG C, it is finally cooled to room temperature, obtain faint yellow acicular crystal, as 4' phenyl 2,2 ':6 ', 2 ' ' terpyridyl nitric acid Gd coordination compound;The complex belongs to rhombic system, and space group is Pbca .The present invention has many advantages, such as simple for process, of low cost, reproducible, has successfully synthesized Gd coordination compound, certain foundation is provided for the complex of synthesizing rare-earth metal.
priorityDate 2018-04-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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