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filingDate 2017-12-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-01-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2021-01-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-108546485-B
titleOfInvention High-solid-content organic-inorganic hybrid resin and preparation method thereof
abstract The invention discloses a high solid content organic-inorganic hybrid resin and a preparation method thereof, and the raw material group for preparing the resin comprises: 40-60 wt% of an acrylate monomer mixture; 2-5 wt% of ethyl orthosilicate; 0.1-1 wt% of a silane coupling agent; 5-20 wt% of hydroxyl-terminated polydimethylsiloxane; 0.5-5 wt% of an initiator; 0.5-4 wt% of a chain transfer agent; 20-40 wt% of a mixed solvent; 0.0001-0.001 wt% of catalyst. The preparation method comprises the steps of mixing tetraethoxysilane and silane coupling agent, preparing modified inorganic silica sol by a sol-gel method, heating, gradually dropping acrylic monomer mixture, initiator and chain transfer agent, carrying out free radical polymerization, cooling after reacting for a period of time, adding hydroxyl-terminated polysiloxane and organic tin catalyst, and uniformly mixing to obtain the designed organic-inorganic hybrid resin with high solid content. The prepared resin has high solid content, meets the requirement of environmental protection, has excellent corrosion resistance and weather resistance after being cured, and can be used in the field of metal corrosion resistance.
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