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filingDate 2018-05-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-05-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2021-05-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-108545706-B
titleOfInvention Treatment method of tellurium-containing waste liquid
abstract The invention provides a method for treating tellurium-containing waste liquid, which comprises the following steps: s1, concentrating and crystallizing the tellurium-containing waste liquid to respectively obtain copper sulfate and crystallization mother liquor; the tellurium-containing waste liquid contains tellurium elements, copper elements and sulfuric acid; s2, reducing the crystallization mother liquor by using a reducing agent to respectively obtain tellurium copper slag and a reduced liquid; s3, carrying out acidic oxidation leaching on the tellurium copper slag by adopting an acid solution and an oxidant to obtain an acidic leaching solution; the acid solution is a hydrochloric acid solution or a sulfuric acid solution; s4, carrying out solid-liquid separation on the acidic leaching solution, adjusting the pH value of a liquid phase to 12-14 by using sodium hydroxide, and simultaneously heating to a boiling state for reaction to obtain an alkaline conversion solution; s5, carrying out acid hydrolysis on the alkaline conversion solution to obtain a tellurium dioxide product. The technical scheme realizes the step-by-step recovery of copper and tellurium, has good copper and tellurium separation effect, high comprehensive recovery rate of copper and tellurium, low cost and increased economic benefit.
priorityDate 2018-05-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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