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filingDate 2018-01-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2020-12-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2020-12-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-108295878-B
titleOfInvention Keggin type phosphotungstic acid composite zirconium-based metal-organic framework photocatalyst and preparation method thereof
abstract The invention relates to a Keggin type phosphotungstic acid composite zirconium-based metal-organic framework photocatalyst and a preparation method thereof. The technical scheme is as follows: mixing zirconium tetrachloride, N-dimethylformamide and hydrochloric acid, and ultrasonically dissolving to obtain a zirconium tetrachloride mixed solution; dissolving 2-amino terephthalic acid in N, N-dimethylformamide to obtain an organic ligand solution. Mixing and stirring a zirconium tetrachloride solution and an organic ligand solution to obtain a precursor solution of a zirconium-based metal-organic framework compound, adding Keggin-type phosphotungstic acid, and stirring to obtain a Keggin-type phosphotungstic acid composite zirconium-based metal-organic framework photocatalyst precursor solution; and then transferring the mixture into a reaction kettle, performing hydrothermal reaction, centrifuging, washing and drying to obtain the Keggin type phosphotungstic acid composite zirconium-based metal-organic framework photocatalyst. The method has the advantages of simple process and strong operability, and the prepared product can improve the separation of photo-generated electron-hole pairs in the photocatalysis process and has excellent hydrogen production performance by decomposing water with visible light.
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