http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-108276453-A

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filingDate 2018-01-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_bc7da3566f07e31a3bd540e56b063313
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publicationDate 2018-07-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-108276453-A
titleOfInvention Symmetrical four teeth Phosphine ligands ferrous metal catalyst of one kind and its preparation method and application
abstract The invention discloses a kind of symmetrical four teeth Phosphine ligands ferrous metal catalyst and its preparation method and application.The structure of the symmetrical four teeth Phosphine ligands ferrous metal catalyst is the octahedra model structure of hexa-coordinate, and structural formula is as shown in following formula I: The invention also discloses the preparation methods of symmetrical four teeth Phosphine ligands ferrous metal catalyst, include the following steps:Reactant A and solvent are mixed to get white suspension B;Molysite and solvent are mixed to get mixed liquor C;By mixed liquor C and suspension B hybrid reactions, symmetrical four teeth Phosphine ligands ferrous metal catalyst is obtained;Wherein, the structural formula of the reactant A is: Or It is formic acid that the symmetrical four teeth Phosphine ligands ferrous metal catalyst of the present invention, which can restore to effective selectivity carbon dioxide, selects performance to reach 97.25%, and obtain methanol by forming an amidated intermediate in the presence of diethylamine.
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priorityDate 2018-01-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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