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filingDate 2018-02-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2020-04-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2020-04-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-108250223-B
titleOfInvention Binuclear copper (II) complex and preparation method and application thereof
abstract The invention discloses a binuclear copper (II) complex and a preparation method and application thereof, wherein the complex is obtained by mixing copper nitrate trihydrate, 1, 3-bis (imidazolyl) propane, anhydrous sodium acetate, DMF (dimethyl formamide) and water, carrying out solvothermal reaction for 3-5 days, cooling, crystallizing, washing and drying, and the chemical formula of the complex is Cu 2 (1,3‑bip) 2 (Ac) 4 1,3-bip represents 1, 3-bis (imidazolyl) propane, Ac ‑ Represents acetate. The complex structure contains two symmetrical divalent copper ions which are connected by two organic bridging ligands 1, 3-di (imidazolyl) propane in a torsion of nearly 180 degrees to form an elliptical ring [ Cu ] 2 (1,3‑bip) 2 ] 4+ Then go through Ac ‑ Further connected to form a zero-dimensional skeleton structure with a polycyclic configuration. The complex has good thermal stability, the degradation rate of the complex to the methyl blue reaches 82% within 105min under the condition of visible light, and the complex can be used as a special photodegradation organic dye catalyst.
priorityDate 2018-02-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 41.