http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-108129506-B
Outgoing Links
| Predicate | Object |
|---|---|
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C29-159 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C29-159 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F7-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C31-04 |
| filingDate | 2017-12-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| grantDate | 2020-05-26-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 2020-05-26-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | CN-108129506-B |
| titleOfInvention | Preparation method of Zr (IV) compound and application of Zr (IV) compound in reduction of carbon dioxide into methanol |
| abstract | A Zr (IV) compound and its application in reducing carbon dioxide to methanol comprises the following steps: 1) in a glove box, the Zr (IV) compound Cl is weighed 3 THF 2 ZrBH 4 In a Schlenk flask, add tetrahydrofuran; 2) the Schlenk flask was taken out of the glove box, connected to a vacuum line and degassed, connected to a balloon filled with carbon dioxide, and reacted at room temperature for 12 hours; 3) after the reaction was complete, hydrolysis gave methanol in 72.5% yield. The invention prepares Zr (IV) compound Cl 3 THF 2 The method of ZrBH is simple, the cost of raw materials is low, and the industrial amplification production is easy to realize. The Zr (IV) compound can reduce carbon dioxide into methanol at normal temperature and normal pressure, and NaCl and boric acid generated in the reaction process can be continuously recycled, so that industrial circulation is realized, and the aim of sustainable production is fulfilled. |
| priorityDate | 2017-12-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 45.