http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-107903399-B
Outgoing Links
| Predicate | Object |
|---|---|
| classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y02P20-584 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-48 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D213-40 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G83-008 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-1691 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07B43-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C231-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D209-14 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C233-05 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G83-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C233-18 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C233-36 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D213-40 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B43-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D209-14 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C231-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C233-13 |
| filingDate | 2017-10-18-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| grantDate | 2020-11-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 2020-11-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | CN-107903399-B |
| titleOfInvention | Preparation method of MOF material for catalyzing amidation reaction |
| abstract | The invention provides a preparation method of a heterogeneous Zr-MOF catalyst and application of the heterogeneous Zr-MOF catalyst in catalytic amidation reaction, and belongs to the field of catalyst synthesis and catalysis. The preparation method comprises the following steps of carrying out solvothermal reaction on aromatic carboxylic acid serving as an organic ligand and zirconium oxychloride in a solution of N, N-dimethylformamide and acetic acid to obtain a metal-organic framework material, wherein the Zr-MOF has a three-dimensional pore structure formed by octahedral cages and tetrahedral cages which are alternately arranged, has a carboxylic acid functional group which does not participate in coordination, has certain acidity, and can be used as a catalyst for amidation reaction. The Zr-MOF catalyst shows high activity in the aspect of catalyzing amidation reaction, is very stable in a catalytic system and convenient to recover and recycle, and the activity is not obviously reduced after 5 times of reaction. |
| priorityDate | 2017-10-18-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 52.