http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-107840967-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_4baf61b82705468dd1ff913b8ce785f7 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G83-008 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G83-00 |
filingDate | 2017-10-01-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_00e97ff266dead30c2e298d23b69499b http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_0f3a936e9ba8f4c4f4b649b2b0914e95 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ad8ec0c9802c735e7ad1b1d78d5510c8 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2e43602070945bd6889208011b7f1581 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b33ec24e99bb63c4d1285a7026c30472 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2b5cdd2447687045c6d5097a41dbc747 |
publicationDate | 2018-03-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-107840967-A |
titleOfInvention | A kind of Cu-Sm heterometallic coordination polymer and preparation method |
abstract | The invention discloses a Cu-Sm heterometallic coordination polymer and a preparation method thereof, the chemical formula of which is {[Sm(H 2 O) 4 (L 1 ) 2 Cu]·0.5(H 2 en)·3H 2 O} n , molecular formula: C 11 H 21 CuN 5 O 15 Sm, molecular weight: 677.22. (1) Dissolve samarium chloride hexahydrate and copper acetate in distilled water; (2) Dissolve 3,5-pyrazoledicarboxylic acid and 2-pyrazinecarboxylic acid in DMF; (3) Dissolve (1), (2 ) the resulting solutions were mixed, adjusted to pH, filtered, and dried to obtain {[Sm(H 2 O) 4 (L 1 ) 2 Cu]·0.5(H 2 en)·3H 2 O} n , wherein L 1 represents 3, 5‑pyrazoledicarboxylic acid removes two carboxyl hydrogen atoms and one hydrogen atom on nitrogen, with three units of negative charge, H 2 en is protonated ethylenediamine, with two units of positive charge. The invention has simple process, low cost and good repeatability. |
priorityDate | 2017-10-01-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 37.