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filingDate 2017-10-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_00e97ff266dead30c2e298d23b69499b
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publicationDate 2018-03-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-107840967-A
titleOfInvention A kind of Cu-Sm heterometallic coordination polymer and preparation method
abstract The invention discloses a Cu-Sm heterometallic coordination polymer and a preparation method thereof, the chemical formula of which is {[Sm(H 2 O) 4 (L 1 ) 2 Cu]·0.5(H 2 en)·3H 2 O} n , molecular formula: C 11 H 21 CuN 5 O 15 Sm, molecular weight: 677.22. (1) Dissolve samarium chloride hexahydrate and copper acetate in distilled water; (2) Dissolve 3,5-pyrazoledicarboxylic acid and 2-pyrazinecarboxylic acid in DMF; (3) Dissolve (1), (2 ) the resulting solutions were mixed, adjusted to pH, filtered, and dried to obtain {[Sm(H 2 O) 4 (L 1 ) 2 Cu]·0.5(H 2 en)·3H 2 O} n , wherein L 1 represents 3, 5‑pyrazoledicarboxylic acid removes two carboxyl hydrogen atoms and one hydrogen atom on nitrogen, with three units of negative charge, H 2 en is protonated ethylenediamine, with two units of positive charge. The invention has simple process, low cost and good repeatability.
priorityDate 2017-10-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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