http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-107722292-B

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filingDate 2017-11-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2020-11-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2020-11-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-107722292-B
titleOfInvention Polyacid-based microporous crystalline material and preparation method thereof
abstract The invention discloses a polyacid-based microporous crystalline state material and a preparation method thereof, which relate to the technical field of polyacid-based microporous crystalline state materials, and the preparation method comprises the following steps: step one, preparing a reaction solution with a pH value of 3-5: dissolving silicotungstic acid, metal cobalt salt and 3, 5-bis (4-pyridyl) pyridine in distilled water to obtain a reaction solution, and then adjusting the pH value of the reaction solution to 3-5 to obtain a reaction solution with the pH value of 3-5; step two, preparing the polyacid-based microporous crystalline material with the three-dimensional metal-three ligand nanometer pore channel structure: adding the reaction solution with the pH value of 3-5 into a polytetrafluoroethylene reaction kettle, reacting for 4 days at 160 ℃, cooling the reaction solution to room temperature, and performing suction filtration to obtain a reddish brown blocky polyhedral crystal; the invention overcomes the problem that the charge, the coordination mode and the space configuration of a single ligand are relatively fixed in the traditional method for preparing the polyacid-based crystalline hybrid material.
priorityDate 2017-11-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 37.