http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-107417900-B
Outgoing Links
Predicate | Object |
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classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G63-823 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G63-08 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G63-83 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G63-08 |
filingDate | 2017-08-14-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2020-09-08-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2020-09-08-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-107417900-B |
titleOfInvention | Zinc coordination polymer catalyst for preparing polyglycolic acid and preparation method thereof |
abstract | The invention relates to a zinc coordination polymer catalyst for preparing polyglycolic acid and a preparation method thereof, and relates to the field of polyglycolic acid catalysts. The chemical formula is [ Zn (BDC) L ], wherein BDC is terephthalate anion, and L is 2,3,5, 6-tetrachloro-N, N' -di (4-pyridine) diamide ligand. The invention adopts zinc nitrate hexahydrate, organic ligand terephthalic acid and 2,3,5, 6-tetrachloro-N, N' -di (4-pyridine) diamide to prepare the zinc coordination polymer containing the quadruple interpenetrating diamond three-dimensional network structure in N, N-dimethylformamide through thermal reaction under a closed condition. The synthesis method disclosed by the invention has high yield and good reproducibility; the obtained crystal has high purity. The zinc coordination polymer has good catalytic activity for catalyzing the ring-opening polymerization of glycolide, and the prepared polyglycolic acid has the weight-average molecular weight of more than 6 ten thousand, and can be applied to the field of medical high polymer materials. |
priorityDate | 2017-08-14-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 38.