http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-107337573-B
Outgoing Links
| Predicate | Object |
|---|---|
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D209-86 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D223-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D279-20 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C211-61 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C209-62 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C211-58 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07B43-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D265-38 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D219-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C211-55 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C209-62 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D223-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D279-20 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D265-38 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B43-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D209-86 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C211-58 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C211-55 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D219-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C211-61 |
| filingDate | 2017-07-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| grantDate | 2020-09-01-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 2020-09-01-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | CN-107337573-B |
| titleOfInvention | Green and novel decarbonylation and hydrogenation method for disubstituted amide derivative |
| abstract | The invention relates to a green new method for decarbonylation and hydrogenation reaction of disubstituted amide derivatives with high efficiency and high selectivity. The non-metal compound triethylborane is used as a catalyst for the first time, and the N, N-diaryl substituted amide and the derivatives thereof can be conveniently catalyzed under mild conditions, and the cheap and easily obtained organic silicon reagent can be used for selectively preparing secondary organic amine products. Compared with the traditional method, the novel method generally has the advantages of wide substrate universality, excellent functional group compatibility, simple operation and the like. The organic silicon reagent is used as a reducing agent to cause the amide compounds to generate decarbonylation hydrogenation reaction for the first time, and a brand-new green reaction strategy is provided for the reduction of amide and derivatives thereof, particularly the laboratory preparation or the industrial production of Organic Light Emitting Diode (OLEDs) material unit-diaryl amine compounds. |
| priorityDate | 2017-07-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 45.