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filingDate 2017-06-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2019-08-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2019-08-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-107325241-B
titleOfInvention Gold complexing ferroso-ferric oxide graft block copolymer hybrid material of multiple response and preparation method thereof
abstract The invention discloses gold complexing ferroso-ferric oxide graft block copolymer hybrid materials of a kind of multiple response and preparation method thereof.First by amidized Fe 3 O 4 It reacts with 2- bromine isobutyl acylbromide in Fe 3 O 4 Surface introduces atom transfer radical polymerization initiator, then modifies hydroxy-ethyl acrylate and tert-butyl methacrylate ester monomer to Fe by Transfer Radical Polymerization 3 O 4 Surface is complexed after hydrolysis and dimercaptosuccinic acid and magnetic block copolymer are esterified with gold nano colloidal sol, obtains the gold complexing Fe of pH, electrochemistry and magnetic multiple response 3 O 4 Grafted propylene acyloxyethyl sulfydryl hemisuccinic acid ester-methacrylic acid block copolymer hybrid material.Hybrid material of the present invention forms spherical micelle in aqueous solution, and particle diameter distribution has high Zeta potential and high stability in 85~155nm, and pH transition point is 5.3~5.9, can make quick response to different acid or alkali environmentsï¼›And the compound electrochemical response and plasma resonance for effectively improving hybrid material of gold nanoparticle.
priorityDate 2017-06-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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