http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-107308993-B
Outgoing Links
| Predicate | Object |
|---|---|
| classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-824 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J35-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-1815 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C01B3-22 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C01B3-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J35-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-22 |
| filingDate | 2017-07-07-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| grantDate | 2019-10-18-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 2019-10-18-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | CN-107308993-B |
| titleOfInvention | The preparation of the support type porous organic polymer catalyst of hydrogen is produced for Catalyzed by Formic Acid |
| abstract | The present invention relates to a kind of preparations of support type porous organic polymer catalyst that hydrogen is produced for the additive-free catalysis of formic acid.The preparation method is: 4- azido Tetrabenzene methane and 2, and cupric sulfate pentahydrate and sodium ascorbate is added in 6- diacetylene pyridine carboxylic acid methyl esters, then hydrolyzes in water and NaOH solution and porous organic polymer is made.It is loading upper palladium acetate and is using NaBH 4 The palladium nano catalytic material of Polymer-supported is obtained after reduction.Porous organic polymer provided by the invention contains carboxylate radical and 2, and two kinds of functional motifs of 6- bis- (triazole) pyridine, they uniformly divide on polymer body skeleton.The 2 of three teeth, (triazole) pyridine of 6- bis- primitive can effectively disperse by chelating ligands and stablize Pd nano particle, and carboxylate group can not only increase the dispersibility of catalysis material in an aqueous medium, it can also promote formic acid deprotonation, so that producing in hydrogen reaction in Catalyzed by Formic Acid has high catalytic activity, selectivity and cyclical stability. |
| priorityDate | 2017-07-07-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 69.