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filingDate 2017-06-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2019-03-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2019-03-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-107115892-B
titleOfInvention Preparation and application of 4-methyl-5-vinylthiazolyl-based polymeric ionic liquid
abstract The invention discloses the preparation and application of a 4-methyl-5-vinylthiazole-based polymerization spherical ionic liquid catalyst. The preparation method of the polymerized spherical ionic liquid is as follows: 4-methyl-5-vinyl thiazole is used as a parent to synthesize a functionalized ionic liquid monomer, and the ionic liquid monomer is further prepared to obtain a polymerized spherical ionic body. This type of catalyst combines the respective advantages of ionic liquids and polymers, and has the characteristics of large specific surface area, high catalytic activity, fast mass transfer rate, good selectivity, high stability, easy recovery and separation, environmental friendliness, and broad prospects for industrial application. The 4-methyl-5-vinylthiazolyl polymerized spherical ionic liquid is made into a new type of catalytic packing and filled in a reactive distillation column for esterification and transesterification continuous reactive distillation, and the ionic liquid and the reaction The organic combination of the rectification process not only has good catalytic activity and high product yield, but also is environmentally friendly and has low corrosiveness, which is of great significance for the realization of process greening.
priorityDate 2017-06-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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