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publicationDate 2017-08-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-107108446-A
titleOfInvention Process for in situ water removal from oxidative esterification reactions using a coupled reactor distillation system
abstract A method for removing water from an oxidative esterification reactor comprises: (a) conducting an oxidative esterification reaction in the reactor; (b) removing a crude product stream from the reactor; (c) removing the crude product stream A first portion of the stream is passed directly to a product recovery zone; (d) a second portion of the crude product stream is introduced into a distillation column to produce a column overhead product stream and a bottoms product stream; (e) at least a portion of the bottoms product stream is passed to and (f) recycling a recycle stream comprising at least a portion of the overhead product stream to the reactor; wherein the recycle stream contains less than 1% by weight (wt%) based on the total weight of the recycle stream ), wherein the weight ratio of the first part to the second part is at least 1:10, and wherein the amount of the recycle stream recycled to the reactor is such that the reactor contains less than or equal to 2.5 wt% of water.
priorityDate 2014-10-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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