| abstract |
The present invention relates to a kind of preparation method of ozone Heterogeneous oxidation solid catalyst, category environmental protection and technical field of chemical engineering catalysts.With attapulgite, diopside, basalt, astrakanite, magnesia spinel and peridotite make carrier, carrier is after lithium hypochlorite and double (acetylacetone,2,4-pentanedione) beryllium reamings, add the bay ammonium chloride of surfactant three and activation process is carried out under ul-trasonic irradiation, then carrier in hydrothermal reaction kettle with composite mineralizer borax and potassium sulfate, catalytic activity auxiliary agent predecessor three (3 trifluoroacetyl group D camphors) praseodymium (III), three cyclopentadiene promethiums, three [N, double (trimethyl silane) amine of N] erbium, trifluoromethayl sulfonic acid thulium (III), catalytic active center predecessor ferrous fumarate, citric acid nickel and Tris(2,2'- bipyridyl) ruthenium (II) chloride hexahydrate, chlordene osmium dipotassium, hydro-thermal reaction is carried out under the effect of the hydroxypropyl dichloride ammonium of ten alkyl dimethyl N ' trimethyls of emulsifying agent N 2, drying is removed after moisture, calcination obtains ozone Heterogeneous oxidation solid catalyst in Muffle furnace. |