| abstract |
The present invention relates to a kind of preparation method of ozone Heterogeneous oxidation solid catalyst, category environmental protection and technical field of chemical engineering catalysts.It is pure with diatom, kyanite, fluorite, glauberite, flyash and taking coal gangue as carrier are after lithium hypochlorite and double (acetylacetone,2,4-pentanedione) beryllium reamings, add surfactant monoalky lether trimethyl ammonium chloride and activation process is carried out under ul-trasonic irradiation, then carrier in hydrothermal reaction kettle with composite mineralizer borax and potassium sulfate, catalytic activity auxiliary agent predecessor three (hexafluoroacetylacetone) yttrium (III) dihydrate, three cyclopentadiene promethiums, three (2, 2, 6, 6 tetramethyls 3, 5 heptadione acid) gadolinium, three (trifluoromethanesulfonimide) ytterbiums, catalytic active center predecessor pyruvic acid isonicotinoyl hydrazone vanadium, cobalt edetate and the golden potassium of tetrachloro, six nitroso rhodium trisodiums, hydro-thermal reaction is carried out under the effect of emulsifying agent stearic acid trimethylamine groups ethanol ester ammonium chloride, drying is removed after moisture, calcination obtains ozone Heterogeneous oxidation solid catalyst in Muffle furnace. |