| abstract |
The present invention relates to a kind of preparation method of ozone Heterogeneous oxidation solid catalyst, category environmental protection and technical field of chemical engineering catalysts.Make carrier after lithium hypochlorite and double (acetylacetone,2,4-pentanedione) beryllium reamings with perlite, albite, potassium feldspar, boromagnesite, illite and raphite, add surfactant 2,6 two（Diethylaminomethyl）4 nonyl phenol Benzene Chloride quaternary ammonium salts carry out activation process under ul-trasonic irradiation, then carrier in hydrothermal reaction kettle with composite mineralizer borax and potassium sulfate, catalytic activity auxiliary agent predecessor 1, 1, 1 trifluoroacetylacetone (TFA) neodymium, ten water holmium oxalates, trifluoromethayl sulfonic acid thulium (III), three (trifluoromethanesulfonimide) ytterbiums, catalytic active center predecessor cobalt edetate, citric acid nickel and the golden potassium of tetrachloro, tetrachloro two is hydrated iridium, hydro-thermal reaction is carried out under the effect of emulsifying agent octadecyldimethyl ethoxy ammonium laurate, drying is removed after moisture, calcination obtains ozone Heterogeneous oxidation solid catalyst in Muffle furnace. |