| abstract |
The present invention relates to a kind of preparation method of ozone Heterogeneous oxidation solid catalyst, category environmental protection and technical field of chemical engineering catalysts.With activated carbon, carnallite, kaolin, red metal and stone, talcum and sal soda masonry carrier are after lithium hypochlorite and double (acetylacetone,2,4-pentanedione) beryllium reamings, add surfactant β hydroxyethyl dimethyls ammonium lauryl sulfate and activation process is carried out under ul-trasonic irradiation, then carrier in hydrothermal reaction kettle with composite mineralizer borax and potassium sulfate, the cyclopentadiene promethium of catalytic activity auxiliary agent predecessor three, three (2, 2, 6, 6 tetramethyls 3, 5 heptadione acid) gadolinium, three [N, double (trimethyl silane) amine of N] erbium, three (trifluoromethanesulfonimide) ytterbiums, catalytic active center predecessor cobalt edetate, zinc lactate, zirconium carbonate ammonium and Tris(2,2'- bipyridyl) ruthenium (II) chloride hexahydrate, hydro-thermal reaction is carried out under the effect of emulsifying agent lauramide propyl-dimethyl dihydroxypropyl ammonium chloride, drying is removed after moisture, calcination obtains ozone Heterogeneous oxidation solid catalyst in Muffle furnace. |