| abstract |
The present invention relates to a kind of preparation method of ozone Heterogeneous oxidation solid catalyst, category environmental protection and technical field of chemical engineering catalysts.With erionite, garnet, light shale haydite, pyrophillite, expanded vermiculite and cacoclasite make carrier after lithium hypochlorite and double (acetylacetone,2,4-pentanedione) beryllium reamings, add surfactant dodecyltrimethyl and activation process is carried out under ul-trasonic irradiation, then carrier in hydrothermal reaction kettle with composite mineralizer borax and potassium sulfate, catalytic activity auxiliary agent predecessor isopropyl scandium oxide (III), three (hexafluoroacetylacetone) yttrium (III) dihydrates, 1, 1, 1 trifluoroacetylacetone (TFA) neodymium, carbonic acid lutetium hydrate, catalytic active center predecessor titanocenes ring substituted salicylic acid complex, pyruvic acid isonicotinoyl hydrazone vanadium, L lucid asparagus amino acid molybdenums and the golden potassium of tetrachloro, hydro-thermal reaction is carried out under the effect of emulsifying agent octadecyldimethyl ethoxy ammonium perchlorate, calcination obtains ozone Heterogeneous oxidation solid catalyst in Muffle furnace after drying removing moisture. |