| abstract |
The present invention relates to a kind of preparation method of ozone Heterogeneous oxidation solid catalyst, category environmental protection and technical field of chemical engineering catalysts.With medical stone, wollastonite, montmorillonite, sylvite, potassium feldspar and boromagnesite make carrier after lithium hypochlorite and double (acetylacetone,2,4-pentanedione) beryllium reamings, add surfactant octadecyl trimethyl ammonium chloride and activation process is carried out under ul-trasonic irradiation, then carrier in hydrothermal reaction kettle with composite mineralizer borax and potassium sulfate, catalytic activity auxiliary agent predecessor isopropyl scandium oxide (III), it is hydrated three acetic acid terbiums, three [N, double (trimethyl silane) amine of N] erbium, three (trifluoromethanesulfonimide) ytterbiums, catalytic active center predecessor titanocenes ring substituted salicylic acid complex, L lucid asparagus amino acid molybdenums, zirconium carbonate ammonium and six nitroso rhodium trisodiums, hydro-thermal reaction is carried out under the effect of emulsifying agent decyl cetyl dimethyl ammonium bromide, drying is removed after moisture, calcination obtains ozone Heterogeneous oxidation solid catalyst in Muffle furnace. |