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filingDate 2017-06-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2017-08-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-107042107-A
titleOfInvention A method for efficiently producing benzaldehyde by catalyzing benzyl alcohol in an alkali-free aqueous phase system at room temperature using air as an oxidant
abstract The invention discloses a method for efficiently producing benzaldehyde by catalyzing benzyl alcohol in an alkali-free aqueous phase system at room temperature using air as an oxidant. The present invention adopts noble metal Pt/metal oxide (zinc oxide, titanium oxide, reduced bismuth oxide) composite system as a catalyst, disperses benzyl alcohol and catalyst in water, and continuously stirs for 5-10 hours under low temperature and dark conditions, and benzaldehyde The selectivity of the production can reach more than 99%, and the yield is maintained in the range of 75-100% depending on the type of carrier. Positive effects of the present invention: 1. The reaction can be carried out at a lower temperature such as room temperature at 25° C.; 2. The cheap air is used as an oxidant, which overcomes the pollution problem of high-priced metals such as chromium and manganese as an oxidant to the environment; 3. Reaction The system does not add alkali substances as promoters; 4. There is basically no side reaction in the reaction process, and the selectivity of benzaldehyde formation is kept above 99%; 5. The equipment and operation process of the reaction are simple.
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