| abstract |
The present invention relates to a kind of preparation method of ozone Heterogeneous oxidation solid catalyst, category environmental protection and technical field of chemical engineering catalysts.It is pure with diatom, kyanite, hydrotalcite, alunite, magnesia spinel and peridotite make carrier after lithium hypochlorite and double (acetylacetone,2,4-pentanedione) beryllium reamings, surfactant Cationic surfucant is added after ul-trasonic irradiation progress activation process, carrier in hydrothermal reaction kettle with composite mineralizer borax and potassium sulfate, catalytic activity auxiliary agent predecessor three (hexafluoroacetylacetone) yttrium (III) dihydrate, three cyclopentadiene promethiums, three (6, 6, 7, 7, 8, 8, 8 seven fluorine 2, 2 dimethyl 3, 5 octene diketone) dysprosium (III), three [N, double (trimethyl silane) amine of N] erbium, catalytic active center predecessor pyruvic acid isonicotinoyl hydrazone vanadium, cobalt edetate and Tris(2,2'- bipyridyl) ruthenium (II) chloride hexahydrate, the ammino platinum of dichloro two, hydro-thermal reaction is carried out under the effect of emulsifying agent double-track suspended self-propelled conveyor, calcination obtains ozone Heterogeneous oxidation solid catalyst in Muffle furnace after drying removing moisture. |