| abstract |
The present invention relates to a kind of preparation method of ozone Heterogeneous oxidation solid catalyst, category environmental protection and technical field of chemical engineering catalysts.It is pure with diatom, kyanite, talcum, sal soda stone, cubric niter and dolomite make carrier after lithium hypochlorite and double (acetylacetone,2,4-pentanedione) beryllium reamings, add surfactant monoalky lether trimethyl ammonium chloride and activation process is carried out under ul-trasonic irradiation, then carrier in hydrothermal reaction kettle with composite mineralizer borax and potassium sulfate, catalytic activity auxiliary agent predecessor three (hexafluoroacetylacetone) yttrium (III) dihydrate, three cyclopentadiene promethiums, three (4, 4, (2 thiophene) 1 of 4 trifluoro 1, 3 diacetyl) europium, ten water holmium oxalates, catalytic active center predecessor pyruvic acid isonicotinoyl hydrazone vanadium, cobalt edetate, ethylenediamine pyrocatechol tungsten complex and the hydration iridium of tetrachloro two, in emulsifying agent dodecyl dimethyl（2 hydroxyls）Ethyl ammonium chloride effect is lower to carry out hydro-thermal reaction, and drying is removed after moisture, and calcination obtains ozone Heterogeneous oxidation solid catalyst in Muffle furnace. |