| abstract |
The present invention relates to a kind of preparation method of ozone Heterogeneous oxidation solid catalyst, category environmental protection and technical field of chemical engineering catalysts.With activated carbon, carnallite, kaolin, red metal and stone, flyash and taking coal gangue as carrier after lithium hypochlorite and double (acetylacetone,2,4-pentanedione) beryllium reamings, surfactant diethyl maleate base is added double（Chlorination dodecyl dimethyl ammonium）Activation process is carried out under ul-trasonic irradiation, then carrier in hydrothermal reaction kettle with composite mineralizer borax and potassium sulfate, the cyclopentadiene promethium of catalytic activity auxiliary agent predecessor three, it is hydrated three acetic acid terbiums, three (6, 6, 7, 7, 8, 8, 8 seven fluorine 2, 2 dimethyl 3, 5 octene diketone) dysprosium (III), carbonic acid lutetium hydrate, catalytic active center predecessor cobalt edetate, zinc lactate, ethylenediamine pyrocatechol tungsten complex and six nitroso rhodium trisodiums, hydro-thermal reaction is carried out under the effect of emulsifying agent methyl chloride acryloyloxyethyl trimethyl ammonium, drying is removed after moisture, calcination obtains ozone Heterogeneous oxidation solid catalyst in Muffle furnace. |