| abstract |
The present invention relates to a kind of preparation method of ozone Heterogeneous oxidation solid catalyst, category environmental protection and technical field of chemical engineering catalysts.It is pure with diatom, kyanite, hydrotalcite, alunite, aluminium hydroxide and reddish black masonry carrier are after lithium hypochlorite and double (acetylacetone,2,4-pentanedione) beryllium reamings, add surfactant Cationic surfucant and activation process is carried out under ul-trasonic irradiation, then carrier in hydrothermal reaction kettle with composite mineralizer borax and potassium sulfate, catalytic activity auxiliary agent predecessor three (hexafluoroacetylacetone) yttrium (III) dihydrate, three cyclopentadiene promethiums, three (6, 6, 7, 7, 8, 8, 8 seven fluorine 2, 2 dimethyl 3, 5 octene diketone) dysprosium (III), trifluoromethayl sulfonic acid thulium (III), catalytic active center predecessor pyruvic acid isonicotinoyl hydrazone vanadium, cobalt edetate and six nitroso rhodium trisodiums, the ammino palladium of dichloro four, hydro-thermal reaction is carried out under the double decyl dimethyl ammonium bromide effects of emulsifying agent, drying is removed after moisture, calcination obtains ozone Heterogeneous oxidation solid catalyst in Muffle furnace. |