| abstract |
The present invention relates to a kind of preparation method of ozone Heterogeneous oxidation solid catalyst, category environmental protection and technical field of chemical engineering catalysts.With erionite, garnet, medical stone, wollastonite, cubric niter and dolomite make carrier, carrier is after lithium hypochlorite and double (acetylacetone,2,4-pentanedione) beryllium reamings, dodecyltrimethyl is added to carry out after activation process under ul-trasonic irradiation, activated carrier in hydrothermal reaction kettle with composite mineralizer borax and potassium sulfate, catalytic activity auxiliary agent predecessor isopropyl scandium oxide (III), three (hexafluoroacetylacetone) yttrium (III) dihydrates, four (2, 2, 6, 6 tetramethyls 3, 5 heptadione acid) cerium (IV), ten water holmium oxalates, catalytic active center component predecessor titanocenes ring substituted salicylic acid complex, pyruvic acid isonicotinoyl hydrazone vanadium, cobalt edetate and the hydration iridium of precious metal chemical complex tetrachloro two, hydro-thermal reaction is carried out under the double dodecyl dimethyl ammonium effects of chlorination, drying removes moisture, calcination obtains ozone Heterogeneous oxidation solid catalyst in Muffle furnace. |