| abstract |
The present invention relates to a kind of preparation method of ozone Heterogeneous oxidation solid catalyst, category environmental protection and technical field of chemical engineering catalysts.With attapulgite, diopside, montmorillonite, sylvite, aluminium hydroxide and reddish black masonry carrier, carrier is after lithium hypochlorite and double (acetylacetone,2,4-pentanedione) beryllium reamings, after the double hydroxyethyl ammoniums of octadecyl methyl 2 of addition surfactant chlorination are handled under ul-trasonic irradiation, carrier in hydrothermal reaction kettle with composite mineralizer borax and potassium sulfate, catalytic activity auxiliary agent predecessor three (3 trifluoroacetyl group D camphors) praseodymium (III), 1, 1, 1 trifluoroacetylacetone (TFA) neodymium, it is hydrated three acetic acid terbiums, three (trifluoromethanesulfonimide) ytterbiums, catalytic active center component predecessor ferrous fumarate, cobalt edetate, tetrachloro two is hydrated iridium, the ammino platinum of dichloro two, hydro-thermal reaction is carried out under the effect of emulsifying agent lauramide propyl-dimethyl dihydroxypropyl ammonium chloride, drying is removed after moisture, calcination obtains ozone Heterogeneous oxidation solid catalyst in Muffle furnace. |