| abstract |
The present invention relates to a kind of preparation method of ozone Heterogeneous oxidation solid catalyst, category environmental protection and technical field of chemical engineering catalysts.With erionite, garnet, medical stone, wollastonite, fluorite and glauberite make carrier after lithium hypochlorite and double (acetylacetone,2,4-pentanedione) beryllium reamings, add surfactant dodecyltrimethyl and surface activation process is carried out under ul-trasonic irradiation, then carrier in hydrothermal reaction kettle with composite mineralizer borax and potassium sulfate, catalytic activity auxiliary agent predecessor isopropyl scandium oxide (III), three (hexafluoroacetylacetone) yttrium (III) dihydrates, four (2, 2, 6, 6 tetramethyls 3, 5 heptadione acid) cerium (IV), three cyclopentadiene promethiums, the general titanocenes ring substituted salicylic acid complex of catalytic active center predecessor, pyruvic acid isonicotinoyl hydrazone vanadium, cobalt edetate and two thiocyanatos silver（I）Sour potassium, carries out hydro-thermal reaction under the double eight alkyl dimethyl ammonium chlorides effects of emulsifying agent, and drying removes after moisture that calcination obtains ozone Heterogeneous oxidation solid catalyst in Muffle furnace. |