| abstract |
The present invention relates to a kind of preparation method of ozone Heterogeneous oxidation solid catalyst, category environmental protection and technical field of chemical engineering catalysts.With erionite, garnet, diatom is pure, kyanite, potassium feldspar and boromagnesite make carrier after lithium hypochlorite and double (acetylacetone,2,4-pentanedione) beryllium reamings, add dodecyltrimethyl and carry out activation process through ul-trasonic irradiation, then carrier in hydrothermal reaction kettle with composite mineralizer borax and potassium sulfate, catalytic activity auxiliary agent predecessor isopropyl scandium oxide (III), three (hexafluoroacetylacetone) yttrium (III) dihydrates, three (3 trifluoroacetyl group D camphors) praseodymiums (III), three (trifluoromethanesulfonimide) ytterbiums, catalytic active center predecessor titanocenes ring substituted salicylic acid complex, pyruvic acid isonicotinoyl hydrazone vanadium, cupric glutamate and chlordene osmium dipotassium, hydro-thermal reaction is carried out under the effect of the hydroxypropyl dichloride ammonium of emulsifying agent N dodecyl dimethyl N ' trimethyls 2, calcination obtains ozone Heterogeneous oxidation solid catalyst in Muffle furnace after drying removing moisture. |