| abstract |
The present invention relates to a kind of preparation method of ozone Heterogeneous oxidation solid catalyst, category environmental protection and technical field of chemical engineering catalysts.The preparation method is to make carrier with activated carbon, carnallite, montmorillonite, sylvite, potassium feldspar and boromagnesite porous material, and carrier is modified through lithium hypochlorite and double (acetylacetone,2,4-pentanedione) beryllium reamings, adds surfactant diethyl maleate base double（Chlorination dodecyl dimethyl ammonium）Surface activation process is carried out under ul-trasonic irradiation, then ultrasonic surface activated carrier in hydrothermal reaction kettle with composite mineralizer borax and potassium sulfate, the cyclopentadiene promethium of catalytic activity auxiliary agent predecessor three, three (6, 6, 7, 7, 8, 8, 8 seven fluorine 2, 2 dimethyl 3, 5 octene diketone) dysprosium (III), three [N, double (trimethyl silane) amine of N] erbium, three (trifluoromethanesulfonimide) ytterbium Rare-earth chemicals, catalytic active center component predecessor normal transition metallo-organic compound cobalt edetate, zinc lactate and the golden potassium of precious metal chemical complex tetrachloro, tetrachloro two is hydrated iridium, hydro-thermal reaction is carried out under the effect of emulsifying agent palmitic acid dimethylamino-ethanol ester ammonium chloroacetate, reaction product drying is removed after moisture, in Muffle furnace, calcination obtains ozone Heterogeneous oxidation solid catalyst under certain temperature. |