| abstract |
The present invention relates to a kind of preparation method of ozone Heterogeneous oxidation solid catalyst, category environmental protection and technical field of chemical engineering catalysts.The preparation method is to use activated carbon, carnallite, illite, raphite, magnesia spinel and peridotite porous mineral materials make carrier, carrier is modified through lithium hypochlorite and double (acetylacetone,2,4-pentanedione) beryllium reamings, add surfactant dimethyl hexadecyl base ethyl sulfuric acid ethyl ester ammonium and surface activation process is carried out under ul-trasonic irradiation, then the composite mineralizer that ultrasonic surface activated carrier is constituted in hydrothermal reaction kettle with borax and potassium sulfate, acetylacetone,2,4-pentanedione samarium, three (4, 4, (2 thiophene) 1 of 4 trifluoro 1, 3 diacetyl) europium, trifluoromethayl sulfonic acid thulium (III), three (trifluoromethanesulfonimide) ytterbium rare earth compound catalytic activity auxiliary agents, cobalt edetate, L lucid asparagus amino acid molybdenums, tetrachloro gold potassium, the transition metal-catalyzed activated centre component of Tris(2,2'- bipyridyl) ruthenium (II) chloride hexahydrate, hydro-thermal reaction is carried out under the effect of emulsifying agent dodecanamide propyl trimethyl sulfate methyl ammonium, reaction product drying is removed after moisture, in Muffle furnace, calcination obtains ozone Heterogeneous oxidation solid catalyst under certain temperature. |